Which of the following statements about quantum numbers

  • Madeline Christine Lowry – CHEM 107 – Dr. Bro
    Problem Set #5

    1

    /res/tamu/lsbrown/Set5/Set5.page
    Set 5 header
    Problem Set #5 is due Tuesday night, October 15, at
    11:59 PM.

    Problems 4 & 5
    4. How many orbitals in any atom can have the given designation : 4p?
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    Problem 1
    Due date: Tue Oct 15 11:59:59 pm 2013 (CDT)
    1. Which of the following statements about quantum numbers are true? (Use the drop down menus to choose "True" or
    "False" for each statement. You must get all of the statements
    correct at the same time.)




    Choices: True, False.
    The labels on atomic orbitals (1s, 2p, etc.) are based on
    quantum numbers.
    Quantum numbers describe the number of protons and
    neutrons in an atom.
    n, l, ml, and ms are quantum numbers.
    The ms quantum number has just 2 allowed values.
    One quantum number can fully describe any atomic
    orbital.

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    Problem 2
    2. Determine whether or not each set of quantum numbers
    shown could correctly describe an electron in an atom. (Use
    the drop down menus to choose "Possible" or "Impossible" for
    each statement. You must get all of the statements correct
    at the same time.)




    Choices: Impossible, Possible.
    n = 3; l = 0; ml = 0; ms = -1/2
    n = 5; l = 3; ml = -2; ms = -1
    n = 3; l = -1; ml = 0; ms = 1/2
    n = 3; l = 1; ml = 2; ms = 1/2
    n = 3; l = 1; ml = -1; ms = -1/2

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    Problem 3
    3. What subshell corresponds to the following quantum numbers: n = 2, l = 1? (e.g. – 1s,2s,2p,4f)
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    5. How many orbitals in any atom can have the following
    quantum number: n = 2?
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    Problem 6
    6. According to the aufbau principle, which subshell is filled
    after the 3p subshell?
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    Problem 7
    7.
    Match each element with its full groundstate electron configuration.
    (Enter the 6 correct letters, in order:
    BADCEG, FBAGDC, etc.).
    1) Sr
    A. 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s1
    2) Se
    B. 1s2 2s2 2p6 3s2 3p2
    3) Cl
    C. 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6
    4) Kr
    D. 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p4
    5) Rb
    E. 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2
    6) Si
    F. 1s2 2s2 2p6 3s2 3p5
    G. 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p3

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    Problem 8
    8.
    Match each element with the full groundstate electron configuration of the monatomic ion
    it is most likely to form.
    (Enter the 6 correct letters, in order:
    BABCEG, FBAGCC, etc.).
    1) Mg
    A. 1s2
    2) Li
    B. 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6
    3) Na
    C. 1s2 2s2 2p6 3s2
    4) N
    D. 1s2 2s2 2p6
    5) Br
    E. 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p5
    6) S
    F. 1s2 2s2 2p6 3s2 3p4
    G. 1s2 2s2 2p6 3s2 3p6
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    Problem 9

    Madeline Christine Lowry – CHEM 107 – Dr. Bro
    Problem Set #5

    3

    9. Arrange the following atoms in order of increasing atomic
    radii. Use the drop down lists to indicate your choice, with 1
    as the smallest radius and 6 as the largest radius.
    Kr
    Ar
    He
    Ne
    Xe
    At
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    Problem 10
    10. Arrange the members of the following set of elements
    in order of increasing first ionization energies. (Use the drop
    down lists to indicate your choice, with 1 as the smallest IE
    and 6 as the largest IE.)
    Li
    Cs
    Na
    K
    Rb
    Fr
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    Problem 11
    11. Arrange the following ions in order of increasing size.
    (Use the drop down menus, and choose 1 for the smallest
    through 5 for the largest.)
    Mg2+
    O2−
    Na+
    N3−
    Al3+

    12. Which of the following statements are true? (Use the
    drop down menus to choose "True" or "False" for each statement. You must get all six statements correct.)




    Choices: True, False.
    Non-metals generally have more negative electron affinities than metals.
    Elements in the same row of the periodic table tend to
    have similar chemical properties.
    The more negative an element’s electron affinity is, the
    more likely that element is to form an anion.
    Electronegativity is a measure of the relative tendency
    of an atom to attract the electrons of a chemical bond
    in which it participates.
    Electronegativity is the tendency of an atom to lessen
    its electron density when bonded to another atom.
    Elements in the same column of the periodic table tend
    to have similar chemical properties.

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    Problem 13
    13. Using electronegativity arguments, classify the following
    diatomic molecules as nonpolar (N), polar (P), or ionic (I).
    (Use the drop down menus to choose your answers; you must
    get all 5 right at the same time.)





    Choices: N, P, I.
    RbO
    F2
    NaF
    HCl
    GaAs

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    Problem 12

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